INVESTIGATION OF FLUORO COMPOUNDS FOR THERMAL PROTECTION.

Abstract

The thermal degradation of halo-polymers was studied in relationship to possible processes of thermal protection. The kinetics and energetics of the thermal degradation of polyethylene, polyvinyl fluoride, polyvinylidene fluoride, polyvinyltrifluoroethylene, polytetrafloroethylene, polyvinyl chloride, and polyvinylidene chlorofluoride, were investigated by thermogravimetric analysis (TGA) and differential thermal analysis (DTA). It was concluded that energy absorption of endothermic decomposition is not a major factor in the thermal protection afforded by these polymers, nor does endothermic decmposition polymers. Theoretical and experimental studies were made to relate smoke formation of thermal protection. The results support, but do not prove, the decomposition of a materials is a significant factor in the protection afforded against high intensity thermal radiation. (Author-PL)

Document Details

Document Type
Technical Report
Publication Date
Apr 18, 1963
Accession Number
AD0438520

Entities

People

  • J. M. Butler
  • L. E. Erbaugh

Organizations

  • Monsanto

Tags

DTIC Thesaurus Topics

  • Biomedical And Dental Materials
  • Composite Materials
  • Decomposition
  • Degradation
  • Dielectric Polymers
  • Differential Thermal Analysis
  • Films
  • Fluorides
  • Materials
  • Plastics
  • Polymeric Films
  • Polymers
  • Polyvinylidenes
  • Polyvinyls
  • Resins
  • Thermal Analysis
  • Thermal Radiation

Fields of Study

  • Chemistry

Readers

  • Combustion science or combustion engineering.
  • Polymer Science and Engineering.
  • Thermal Physics or Thermal Science.