ELECTROCHEMICAL STUDIES IN THE SYNTHESIS OF N-F COMPOUNDS

Abstract

This report describes work which has been devoted to the development of a suitable working electrode for use in electrochemical fluorination studies in anhydrous HF (AHF). Investigations of possible working electrodes have involved antimony, bismuth, silver, aluminum, titanium, cobalt, iron, and monel. Antimony, bismuth, and silver show a high anodic dissolution rate in AHF, while the other metals studied show passive behavior. Of the latter metals only monel formed a protective coating which permitted appreciable fluorine evolution to occur.

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Document Details

Document Type
Technical Report
Publication Date
Jul 09, 1964
Accession Number
AD0442627

Entities

People

  • Gerhard M. Schmid
  • Larry D. Fiel
  • Larry G. Spears
  • Wallace E. Harrell Jr.

Organizations

  • Tracor

Tags

DTIC Thesaurus Topics

  • Aluminum
  • Anodic Polarization
  • Antimony
  • Body Weight
  • Corrosion
  • Electrodes
  • Electrolytic Cells
  • Films
  • Fluorides
  • Halocarbon Plastics
  • Materials
  • Measurement
  • Personal Information Managers
  • Platinum
  • Polarization
  • Resistance
  • Schematic Diagrams

Readers

  • Organic Chemistry
  • Thin Film Deposition Science.