THE MECHANISM OF THE ACETYLENE-OXYGEN REACTION IN SHOCK WAVES

Abstract

The oxidation of acetylene was studied using sufficiently high gas densities and concentrations of inert gas to keep the reaction isothermal and reduce boundary layer effects. The induction periods and exponential time constants of the oxidation were measured using the observations of: (1) chemiluminescence and gas conductivity in incident and in reflected shock waves, and (2) total ionization and product formation using a time-of-flight mass spectrometer in reflected shock waves. The results are internally consistent, and the time constants are best represented by a logarithmic equation.

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Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1964
Accession Number
AD0445101

Entities

People

  • G. B. Kistiakowsky
  • G. P. Glass
  • H. Niki
  • J. V. Michael

Organizations

  • Harvard University

Tags

Communities of Interest

  • Advanced Electronics
  • C4I
  • Energy and Power Technologies
  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Acetylenes
  • Alkynes
  • Boundaries
  • Boundary Layer
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemistry
  • Electrons
  • Equations
  • Heat Of Formation
  • Ionization
  • Luminescence
  • Mass Spectrometers
  • Measurement
  • Oxidation
  • Shock Waves
  • Spectrometers

Readers

  • Combustion science or combustion engineering.
  • Electromagnetic Wave Scattering and Antenna Radiation Engineering
  • Structural Dynamics.