ELECTRODE KINETICS AT OPEN CIRCUIT AT THE STREAMING MERCURY ELECTRODE II. EXPERIMENTAL RESULTS.
Abstract
The shift of potential at open circuit of a streaming mercury electrode (S.M.E.) was determined and anlyzed for control by diffusion or charge transfer and for mixed control by diffusion and charge transfer. The following systems were investigated: Hg(I) in 1 M perchloric acid, Cr(III)/Cr(II) in 1 M potassium chloride and V(III)/V(II) in 1 M perchloric acid. The charging current of the S.M.E. was also investigated and observations were made on the discharge of Hg(I) and Hg(II) with mixed control by diffusion and migration. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Feb 01, 1965
- Accession Number
- AD0459417
Entities
People
- G. Torsi
- Paul Delahay
- V. S. Srinivasan
Organizations
- Louisiana State University