ELECTROMETRIC METHODS OF END-POINT INDICATION FOR THE ARGENTOMETRIC TITRATION OF MICROGRAM AMOUNTS OF CHLORIDE.

Abstract

Potentiometry, a polarisation end-point method and differential electrolytic potentiometry have been investigated for sensitivity of endpoint indication for the routine argentometric determination of up to 50 micrograms of chloride ion. A small volume and high acetone concentration were necessary for optimum indication by the three methods. Potentiometry and differential electrolytic potentiometry required ca 30 min for a titration; polarisation end-point required ca 10 min. End-points were clearly indicated without plotting curves to =0.07 microgram with 0.004 N silver nitrate as titrant. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1965
Accession Number
AD0460679

Entities

People

  • J. R. Webb

Organizations

  • Royal Aircraft Establishment

Tags

DTIC Thesaurus Topics

  • Chemical Compounds
  • Chlorides
  • Physical Properties
  • Plotting
  • Polarization
  • Sensitivity
  • Silver Compounds
  • Titration
  • Volume

Fields of Study

  • Chemistry

Readers

  • Analytical Chemistry
  • Calculus or Mathematical Analysis
  • Materials Science and Engineering.