RESEARCH ON SYNTHESIS OF UNSATURATED FLUOROCARBON COMPOUNDS.

Abstract

Allyl magnesium bromide has been found to react with a number of fluoroolefins to give reasonable yields of the 1,4-dienes. The reaction of fluoroolefins with vinyl organometallics and the mono- and di-metallic acetylenes proved unsuccesful. The codimerization of CF2=CFBr and CF2CFCH2CH2Br was carried out and some reactions of the product were investigated. The preparation of 1,2-bis(pentafluorophenyl)hexafluorocyclo-1-butene is described. The reaction of highly fluorinated ketones with some organometallic compounds to give tertiary carbinols has been investigated. Silanes with trifluorovinyl group have been prepared. (Author)

Document Details

Document Type
Technical Report
Publication Date
Mar 31, 1964
Accession Number
AD0462259

Entities

People

  • A. C. Wright
  • David Sayers
  • Jim Heyes
  • Paul Tarrant
  • Ward Oliver

Organizations

  • University of Florida

Tags

DTIC Thesaurus Topics

  • Acetylenes
  • Acyclic Hydrocarbons
  • Alkenes
  • Alkynes
  • Carbinols
  • Chemical Compounds
  • Fluorinated Hydrocarbons
  • Fluoropolymers
  • Hydrocarbons
  • Magnesium
  • Organic Compounds
  • Organometallic Compounds

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry