POLYMORPHISM IN PALLADIUM (II) CHLORIDE.
Abstract
A structure of PdCl2 has been established which is often given as an example of a linear, infinite-chain, inorganic molecule. Evidence is presented which indicates that this structure is of a high temperature polymorph which can exist metastably at room temperature for many months, and that a third modification PdCl2 exists at higher temperatures still. Structural details of the latter, as well as of the form thermodynamically stable at room temperature, are as yet not known. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Aug 01, 1965
- Accession Number
- AD0468912
Entities
People
- J. R. Soulen
- William H. Chappell Jr.