DEUTERIO DERIVATIVES OF 2,3-DICARBANHEXABORANE(8); FORMATION OF 2,3-DICARBAEPTA- HYDROHEXABORATE(1).
Abstract
Treatment of 2,3-dicarbahexaborane(8) with sodium hydride in diglyme results in the liberation of one mole of H2 and the formation of 2,3-C2B4H7(-) ion. Protonation of the ion with HCl or DCl gives 2,3-dicarbahexaborane(8) and a deuterio derivative, respectively. Bridge deuteration is indicated from B-11 and H-1 n.m.r. and infrared data. An exchange between deuteriodiborane and 2,3-dicarbahexaborane(8) at 100 C results in protium-deuterium exchange in the 4,5,6 terminal positions. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Sep 01, 1965
- Accession Number
- AD0470539
Entities
People
- Gary B. Dunks
- Thomas Onak
Organizations
- California State University, Los Angeles