CYCLIZATIONS OF 2-CYANO-3-SUBSTITUTED CINNAMONTRILES.

Abstract

Synthesis and cyclization of 5,5-dicyano-4-phenyl-4-pentenoic acid and ethyl 2-carbethoxy-5,5-dicyano-2-hydroxyl -4-phenyl -4-pentenoate are studied. Cyclization of the above 2-cyano-3-substituted cinnamonitriles in sulfuric acid yields 2-carboxamido-3- (2-carbethoxy) -1-indenone and 2-carboxamido-3- (2-carboxy-2-hydroxy -ethylidene)-2-indanone, respectively. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1966
Accession Number
AD0479150

Entities

People

  • G. C. Denault
  • H. H. Takimoto
  • S. Hotta

Organizations

  • The Aerospace Corporation

Tags

Fields of Study

  • Chemistry

Readers

  • Data Mining and Knowledge Discovery.
  • Organic Chemistry