PHYSICAL CHEMISTRY OF TETRAKIS (DIMETHYLAMINO) ETHYLENE. III. CHEMILUMINESCENCE QUANTUM YIELD AT 30 deg. C.

Abstract

The chemiluminescence quantum yield for a n-decane solution of tetrakis(dimethylamino)ethylene (TMAE), oxygen, and 1-octanol at 30 C was determined under a wide range of experimental conditions. It is found that a maximum possible quantum yield of 3.6% can be expected. The yield is found to depend upon TMAE/(11.5(TMAE) + 1) so that it decreases with decreasing TMAE concentration. A discussion is given concerning yields reported by other workers.

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Document Details

Document Type
Technical Report
Publication Date
Apr 01, 1966
Accession Number
AD0480563

Entities

People

  • A. N. Fletcher
  • C. A. Heller

Organizations

  • Naval Air Weapons Station China Lake

Tags

Communities of Interest

  • Advanced Electronics
  • Air Platforms
  • Counter WMD
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Abstracts
  • Chemical Kinetics
  • Chemical Synthesis
  • Chemistry
  • Energy
  • Energy Bands
  • Geometry
  • Materials
  • Measurement
  • Military Research
  • Munitions
  • Optics
  • Physical Chemistry
  • Quantum Yields
  • Radiation
  • Refractive Index
  • Weapons

Fields of Study

  • Chemistry

Readers

  • Combustion science or combustion engineering.
  • Organic Chemistry

Technology Areas

  • Quantum Computing