SYNTHESIS OF SELECTED OXIDANTS. REACTIONS OF MANGANESE COMPOUNDS WITH DINITROGEN PENTOXIDE
Abstract
The ain of this investigation was to prepare nitrato complexes of man.anese in its higher oxidation states. The potential of such compounds as powerful oxidants was discussed in a previous report. A review of nitrato complexes with special reference to those of manganese is presented here. Particular emphasis is placed on the infrared spectra of these compounds since they provide important structural information. A brief review of the compounds of manganese in its higher oxidation states is followed by a description of experiments carried out in order to prepare such compounds. Experiments designed to yield the required nitrato complexes are discussed and finally a novel reaction of manganese salts with trialkyl phosphates, analogous to the Arbuzov reaction, is described.
Document Details
- Document Type
- Technical Report
- Publication Date
- Jul 01, 1966
- Accession Number
- AD0486531
Entities
People
- Colin Hewlett
- Hans B. Jonassen
Organizations
- Tulane University of Louisiana