EFFECTS OF POLYMER CHAIN ORIENTATION UPON THE THERMAL CONDUCTIVITY OF POLYMETHYL METHACRYLATE AT LIQUID NITROGEN TEMPERATURES.

Abstract

Measurements of the thermal conductivity of commercial samples of polymethyl methacrylate (Plexiglas) with random and partially oriented polymer chains were made at liquid nitrogen temperatures to provide empirical guidelines into relationships of heat transfer mechanisms of amorphous polymers. Cast samples were formed to have degrees of stretch of one, two, three and four times original length. These samples were found to have thermal conductivities of 1.67, 1.91, 2.05 and 2.10 plus or minus .04 mwatt/cm-K respectively. An extruded sample was determined to have an effective degree of stretch of two. Comparison was made with an empirical model based on component thermal conductivities obtained by partitioning with respect to vibrational modes into longitudinal and one- and three-dimensional transverse components. (Author)

Document Details

Document Type
Technical Report
Publication Date
May 01, 1966
Accession Number
AD0487029

Entities

People

  • Gerald Needham Galstan

Organizations

  • Naval Postgraduate School

Tags

DTIC Thesaurus Topics

  • Conductivity
  • Energy Transfer
  • Heat Transfer
  • Methacrylates
  • Nitrogen
  • Orientation (Direction)
  • Plastics
  • Plexiglas
  • Polymers
  • Polymethyl Methacrylate
  • Resins
  • Thermal Conductivity
  • Three Dimensional
  • Transverse

Readers

  • Mechanical Engineering/Mechanics of Materials.
  • Molecular Photonics/Laser Physics
  • Surface Coatings Technology.