EFFECT OF MANGANESE AND LEAD IN JP FUEL ON HOT CORROSION OF SUPERALLOYS IN MARINE ENVIRONMENT.

Abstract

Methyl cyclopentadienyl manganese tricarbonyl (CI-2) is being considered for use as a smoke suppressent additive in aviation-turbine (JP) fuel. Another organometallic material, tetraethyl lead (TEL), was present in the Jet Mix used for carrier-based operation at one time and caused excessive deterioration of hot section components in aircraft-turbine engines. A screening investigation was conducted to evaluate the effect of manganese, relative to lead, in fuel on hot corrosion of turbine alloys in a marine environment. The six superalloys previously evaluated were included in the investigation using four levels of exhaust-gas temperature, two levels of 'sea salt' in air, and two levels of sulfur in fuel. The concentration of CI-2 selected was ten times the concentration recommended for smoke suppression and the concentration of TEL was ten times the concentration used in Jet Mix. The significance of metal weight loss by test specimens was evaluated by statistical means, using a 95 per cent confidence level. The validity of metal weight loss data was established by metallographic examination of test specimens, which showed a correlation with depth of penetration and the absence of deep intercrystalline attack.

Document Details

Document Type
Technical Report
Publication Date
Aug 25, 1966
Accession Number
AD0489361

Entities

People

  • H. T. Quigg
  • R. M. Schimer

Tags

Communities of Interest

  • Air Platforms

DTIC Thesaurus Topics

  • Additives (Chemicals)
  • Aircrafts
  • Alloys
  • Body Weight
  • Corrosion
  • Environment
  • Exhaust Gases
  • Gases
  • Manganese
  • Material Degradation Processes
  • Materials
  • Metals
  • Organometallic Compounds
  • Superalloys
  • Turbines

Readers

  • Combustion science or combustion engineering.
  • Organic Chemistry
  • Surface Engineering/Surface Coating Technology.