Ionic Fluorine Chemistry.
Abstract
This report describes further attempts to prepare the ClF6 anion. The use of large excesses (up to ClF5:CsF of 120:1) or the use of activated CsF did not result in products containing the desired anion. Conflicting reports have appeared in the literature concerning the existence of a NOF-ClF5 adduct formed at -78 degrees. An investigation of this system showed that, while mixtures of NOF and ClF5 show a negative deviation from Raoult's Law, no solid product is formed. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- May 31, 1969
- Accession Number
- AD0502179
Entities
People
- Donald J. Mangold
- Gene A. Hyde