Inorganic Halogen Oxidizers
Abstract
The new compound chlorine perchlorate, Cl2O4, was synthesized from the action of chlorine fluorosulfate on several perchlorate salts. Characterization data, physical and chemical properties are described. The use of N2O as an oxygen source for the synthesis of ClF3O was successful but offered no advantages over oxygen. A new synthesis of nitryl chloride emerged from the studies of Ca(OCl)2 as an intermediate and involved the action of nitrosyl fluoride, FNO, on calcium hypochlorite. A structural evaluation on chlorine fluorosulfate was carried out from its ir spectrum. C(S) symmetry for ClSO3F was suggested and thermodynamic properties and force constants were computed.
Document Details
- Document Type
- Technical Report
- Publication Date
- Oct 31, 1969
- Accession Number
- AD0505418
Entities
People
- C. B. Lindahl
- C. J. Schack
- D. Pilipovich
- K. O. Christe
- R. D. Wilson