STUDY OF CHEMICAL AGENT DECONTAMINATION SYSTEMS FOR MULTIPURPOSE USE
Abstract
Competitive hydrogen transfer studies were conducted for methyl benzoate, diisopropyl methyl phosphonate (DIMP), GB, GF and HD vs. carbon tetrachloride in each case employing phenylazotriphenylmethane (PAT) as a source of phenyl radicals. The cooxidation of GB with benzaldehyde, and of GF with 2, 2-azobis (isobutyronitrile) (AIBN), indene, and with cyclooctene was investigated at 25 C. The kinetics of the autoxidation of GF in the presence of Co(II) catalyst at 75 to 135 deg C were investigated. In addition, the autoxidation reaction was investigated in the absence of catalyst and in the presence of varying quantities of catalyst. The effect of 2,6-di-tert-butylphenol (DTBP) as an inhibitor was investigated. The autoxidation of HD in the absence and in the presence of Co(II) catalyst at 105 deg C was examined. The use of ferrous phthalocyanine as a heterogeneous catalyst for the autoxidation of GF at 25 deg C was examined. The results obtained are compared with those reported for the autoxidation of carboxylic esters.
Document Details
- Document Type
- Technical Report
- Publication Date
- May 01, 1964
- Accession Number
- AD0600061
Entities
People
- F. A. Serafin
- H. E. Podall
- J. L. Poling
- S. Preis
- Z. Oser
Organizations
- Melpar