CHEMISTRY OF DECABORANE-PHOSPHORUS COMPOUNDS. V. SYNTHESIS AND PHOSPHINATION OF BROMOCARBORANES.
Abstract
Aluminum halide catalyzed bromination of carborane and neocarborane resulted in a stepwise substitution with tri bromocarborane and dibromoneocarborane respectively, as the ultimate products. Further halogenation was achieved with chlorine to give B10H2Br3Cl5C2H2, B10Br2Cl8C2H2, and neo-B10Br2Cl8C2H2. Some reactions of the bromocarboranes including the preparation of phosphorus derivatives are described. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Jul 01, 1964
- Accession Number
- AD0602087
Entities
People
- Hampton D. Smith
- Hansjuergen Schroeder
- Thomas A. Knowles