IODINE FLUOROSULFATES AND IODYL FLUOROSULFATE

Abstract

Iodine (I) fluorosulfate (IOSO2F) and tri-iodine fluorosulfate (I3OSO2F) were prepared by the reaction of iodine with peroxydisulfuryl difluoride (S2O6F2). Their solutions in fluorosulfuric acid have the colors and spectra character istic of the I(+) and I(3+) ions, respectively. Dichlorofluorosulfatoiodine (IC12OSO2F) was produced from chlorine and IOSO2F. Iodine (III) fluorosulfate decomposes slowly when under vacuum at about 80 degrees to 90 degrees to give iodine (I) fluorosulfate, which remains with the unreacted I(OSO2F)3, and the volatile products SO3, IF3(OSO2F)2 and an unidentified substance which may be I(OSO2F)5.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1964
Accession Number
AD0602225

Entities

People

  • C. H. Kennard
  • Friedhelm Aubke
  • George Hamilton Cady

Organizations

  • University of Washington

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Absorption
  • Chemical Compounds
  • Chemical Synthesis
  • Chemistry
  • Chlorine
  • Fluorine
  • Infrared Spectra
  • Liquids
  • Magnetic Resonance
  • Materials
  • Measurement
  • Military Research
  • Nuclear Magnetic Resonance
  • Spectra
  • Universities
  • Visible Spectra
  • X Rays

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry