EVALUATION OF THE MECHANISM OF CORROSION IN CAPILLARIES

Abstract

Mechanisms by which corrosion can occur in a capillary of 2014 aluminum are studied. Both experimental and theoretical techniques are employed in the program. The corrosive media are products of the reaction between: (1) water and fuel (a mixture of hydrazine and dimethyl hydrazine); and (2) water and oxidizer (nitrogen tetroxide). With each of these two reacting systems, one may form two displacement systems. In one case the capillary is initially filled with water which is later displaced by propellant. In the other case the capillary is initially filled with propellant which is later displaced by water. The word capillary refers to a crevice of small diameter open at one end to a propellant tank but closed at the other end. This is intended to include weld cracks, weld porosity, or huckbolt patches. Two configurations were considered in detail: a uniform cylindrical hole and a large cavity connected to a propellant tank by a relatively narrow hole.

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Document Details

Document Type
Technical Report
Publication Date
Jun 22, 1964
Accession Number
AD0602782

Entities

People

  • B. K. Larkin
  • C. C. Fatino
  • P. J. Pizzolato

Tags

Communities of Interest

  • C4I
  • Weapons Technologies

DTIC Thesaurus Topics

  • Aluminum Alloys
  • Aqueous Solutions
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Diffusion
  • Diffusion Coefficient
  • Equations
  • Hydroxides
  • Liquid Phases
  • Liquids
  • Materials
  • Mixtures
  • Propellant Tanks
  • Propellants
  • Rocket Oxidizers
  • Sodium Hydroxide

Readers

  • Combustion science or combustion engineering.
  • Electrical Engineering
  • Materials Science and Engineering.