NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY: ANALYSIS OF THE PROTON SPECTRUM OF CYCLOBUTENE.

Abstract

A complete analysis of the proton n.m.r. spectrum of cyclobutene (I) was made which shows that the couplings between the allylic and vinylic protons, while small, are by no means negligible. The analysis which involved C(13)satellite spectra of ordinary and specifically deuterated cyclobutene gave spin-coupling and chemical shift parameters which predict that cyclobutene should show just two quite sharp peaks in its high-resolution n.m.r. spectrum in agreement with experiment. (Author)

Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1964
Accession Number
AD0605677

Entities

People

  • John D. Roberts
  • Stanko Borcic

Organizations

  • California Institute of Technology

Tags

Communities of Interest

  • Space

DTIC Thesaurus Topics

  • Chemical Shifts
  • Couplings
  • Cyclic Hydrocarbons
  • Cyclobutenes
  • High Resolution
  • Magnetic Resonance
  • Nuclear Magnetic Resonance
  • Quantum Properties
  • Resonance
  • Spectra
  • Spectroscopy

Fields of Study

  • Chemistry

Readers

  • Computational Modeling and Simulation
  • Organic Chemistry
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.

Technology Areas

  • Space