INFLUENCE OF IONIC SOLUTES UPON RELAXATION TIMES,
Abstract
Sin-lattice relaxation times were measured by the 'direct' N.M.R. method for dilute aqueous solutions of Ni(II) in presence of cyanide, halide, acetone, t-butyl alcohol, trimethyl phosphate, edta and trien, for some of these solutes in the absence of paramagnetic ions. Spin-spin relaxation times were used to measure the influence of hydrogen ions on complex formation between water and acetaldehyde or pyruvic acid. Complex formation between methanol and other solvents through hydrogen-bonding was investigated by measurements of chemical shifts, the influence of methoxide ions on multiplet collapse, and indicator measurements. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Jul 01, 1964
- Accession Number
- AD0605723
Entities
People
- V. Gold
Organizations
- King's College London