SPECTROSCOPIC STUDIES: PART 4, THE PREDICTION OF CONFORMATION FROM BOND STRETCHING FREQUENCIES.
Abstract
A study on X.CH2 .CH2 .Y molecules shows that a relation exists between the CX-bond stretching frequency and the electronegativity product CHI (X) CHI (Y) when X and Y are in the trans position. This correlation is used to demonstrate that the gauche isomer is the more stable conformer for ClCH2 .CH2 CN and BrCH2.CH2 CN. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Jul 07, 1964
- Accession Number
- AD0606673
Entities
People
- E. W. Jones
- W. J. Orville-thomas
Organizations
- Aberystwyth University