NEW HYPOFLUORITES CONTAINING NITROGEN

Abstract

Attempts to prepare NF2OF by (1) the fluorination of nitric oxide; (2) the reaction of N2F4 + HgO; and (3) the catalytic fluorination of NF2OSO2F, were unsuccessful. Some preliminary data on the thermal decomposition of NF2OSO2F are included. Catalytic fluorination of trifluoro nitrosomethane yielded (CF3)2NOCF3 which was more completely characterized and very likely CF3(F) NOCF3 is also produced. As the other member of this series, NF2OCF3 was prepared and partially characterized. (CF3)2NOCF3 is stable to at least 200C even in the presence of equimolar amounts of elemental fluorine. The thermal decomposition of CF3C(O)ONO also gives (CF3)2NOCF3 in about 5% yields.

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1964
Accession Number
AD0607616

Entities

People

  • Jean'ne Shreeve

Organizations

  • University of Idaho

Tags

Communities of Interest

  • Ground and Sea Platforms

DTIC Thesaurus Topics

  • Amines
  • Catalytic Reactors
  • Fluorination
  • Fluorine
  • Halocarbon Plastics
  • Hard Copy
  • High Pressure
  • Infrared Spectra
  • Nitrogen
  • Radiation
  • Spectra
  • Ultraviolet Radiation
  • United States

Fields of Study

  • Chemistry

Readers

  • Battery Technology and Engineering
  • Combustion science or combustion engineering.
  • Organic Chemistry