NEW IRON-CONTAINING POLYMERS ON THE BASIS OF FERROCENE AND THEIR ELECTROPHYSICAL PROPERTIES,
Abstract
There were obtained, by means of polyrecombination and condensation polymerization, 14 new polymers based on ferrocene and its derivatives, and their properties were studied. 2. It is shown that the polymers obtained which represent polyconjugate systems possess polyconductor properties. Their specific electrical resistances lie in the interval from 1 x 10 to the 12th power 1 x 10 to the 9th power cm/ohm and the energy of activation in the interval from 0.3 to 1.74 ev (without desorption from the surface). 3. An explanation is given of the role and the effect of the surface adsorption on the semiconductor properties of the polymer of 1, 1'-diacetyl-ferrocene. It is shown that the greater energies observed for the activation are brought about to some degree by the excitation of p1electrons from the valence zone into the zone of conductivity of the macromolecules and basically by the surface adsorption. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Oct 19, 1964
- Accession Number
- AD0608051
Entities
People
- F. F. Machus
- I. I. Patalakh
- L. S. Polak
- T. P. Vishnyakova
- Ya. M. Paushkin
Organizations
- National Air and Space Intelligence Center