THE ANOMALOUS STARK EFFECT OF FLUOROFORM IN THE NU6=1 VIBRATIONAL STATE,

Abstract

It is shown that the paper of Maes and Amat, which explains the anomalous frequencies of the NU6, J = 2 to 1, K = 0 lines in CHF3 and CDF3 by taking into account a strong mixing of K = 0 and K = 2 levels, also predicts accurately, the Stark effect of these transitions. In addition, the perturbing J = 2, K = =2, l = =1 level of the v6 = 1 vibration of CHF3 has been found at the position they predict. Further examination of the NU3 + NU6, J = 2 to 1 line has removed the uncertainty in the assignment of the NU3 + NU6 and NU2, J = 1 to 0 transitions. (Author)

Document Details

Document Type
Technical Report
Publication Date
Oct 27, 1964
Accession Number
AD0611598

Entities

People

  • C. C. Costain

Organizations

  • National Research Council Canada

Tags

DTIC Thesaurus Topics

  • Doppler Effect
  • Frequency
  • Frequency Shift
  • Stark Effect
  • Transitions
  • Uncertainty
  • Vibration

Fields of Study

  • Physics

Readers

  • Molecular Photonics/Laser Physics