ELECTRON PARAMAGNETIC RESONANCE EXPERIMENTS WITH TI(3+) IONS IN RBA1(SO4)2.12H20,
Abstract
The paramagnetic resonance spectrum of the Ti(3+) ion in cubic RbAl(SO4)2. 12H2O single crystals was studied in the (100) and (110) planes at 4.2K with an X-band microwave spectrometer. The spectrum, which consists of a maximum of 12 lines, has been explained by considering a model of 12 magnetic complexes which are related to each other through the symmetry elements of the T(h) = (2/m)3 point group of the Rb alum lattice. For the spin Hamiltonian with S = 1/2 three g factors have been determined--1.895, 1.715, and 1.767--within an accuracy of =0.002, indicating the existence of a crystal electric field of orthorhombic symmetry. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- May 05, 1964
- Accession Number
- AD0611964
Entities
People
- Gerald F. Dionne
Organizations
- McGill University