REACTIONS BETWEEN SECONDARY AMINES AND ORGANO-HALOGENATING AGENTS.
Abstract
Kinetics of chlorine acceptance by succinimide suggests that the negative ionic form of the imide is responsible for the main course of the reaction. Additional data were obtained on the rate of reversible halogen transfer from N-chlorosuccinimide (NCSI) to various secondary amines. Preliminary results on the reactions of quinuclidine with halogenating agents indicate the great stability of the resulting chloroammonium form. The rate of formation of this species from hypochlorous acid and the base was determined. Although the mechanism of breakdown of NCSI in solution has not as yet been solved, several additional bits of information were obtained. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Jul 15, 1964
- Accession Number
- AD0612010
Entities
People
- Takeru Higuchi
Organizations
- University of Wisconsin–Madison