THE THERMAL DECOMPOSITION OF METAL COMPLEXES. XIII. SOME TETRAMMINEPALLADIUM(II) COMPLEXES,
Abstract
The thermal dissociation of the palladium(II) tetramminecomplexes, Pd(NH3)4X (where X is 2Cl, 2Br, 2I, 2NO3, and SO4), was studied by thermogravimetry, DTA, GE, and by analysis of the pyrolysis products. The complexes, except for the nitrate and sulphate, dissociated to give the trans-diammine-complexes, Pd(NH3)2X. The diammine-iodide and bromide complexes dissociated to give the corresponding anhydrous metal halides, PddX2. The stoicheiometry for the thermal dissociation of the Pd(NH3)2X2 complexes, where X was Cl, Br, and I, was determined. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Feb 07, 1964
- Accession Number
- AD0612245
Entities
People
- L. A. Funes
- W. W. Wendlandt
Organizations
- Texas Tech University