A SEMI-EMPIRICAL MO THEORY OF SIGMA ELECTRON SYSTEMS. II. BOND POLARITY AND ELECTRONEGATIVITY,

Abstract

A previously proposed theory (see AD-612 588) is applied to a study of the electronegativity scale and the ionic character of bonds. The general validity of the electronegativity scale and also the relation between the Mulliken and Pauling scales are discussed. The previously defined inductive effect is used as a basis for calculations on MXn-type molecules and on n-alkyl halide molecule. The results are then used for the qualitative interpretation of the experimental dipole moments, nuclear quadrupole coupling constants and fluorine chemical shifts. (Author)

Document Details

Document Type
Technical Report
Publication Date
Mar 10, 1964
Accession Number
AD0612587

Entities

People

  • Hidekazu Hamano

Organizations

  • University of Pennsylvania

Tags

DTIC Thesaurus Topics

  • Chemical Shifts
  • Couplings
  • Dipole Moments
  • Electrons
  • Fluorine
  • Halogenated Hydrocarbons
  • Molecular Orbital Theory
  • Molecules
  • Personality
  • Polarity

Fields of Study

  • Physics

Readers

  • Quantum Chemistry
  • Theoretical Analysis.

Technology Areas

  • Microelectronics