PREPARATION AND PROPERTIES OF BISTRIFLUOROMETHYLSULFURYL PEROXIDE AND TRIFLUOROMETHYL TRIFLUOROMETHANE SULFONATE

Abstract

Electrolysis of trifluoromethanesulfonic acid at -23C yields the unstable compound bistrifluoromethylsulfuryl peroxide which decomposes explosively to perfluoroethane, sulfur trioxide, and the ester, trifluoromethyl trifluoromethanesulfonate.

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Document Details

Document Type
Technical Report
Publication Date
Apr 01, 1965
Accession Number
AD0613524

Entities

People

  • George Hamilton Cady
  • Ronald E. Noftle

Organizations

  • University of Washington

Tags

Communities of Interest

  • Counter IED

DTIC Thesaurus Topics

  • Acids
  • Chemical Analysis
  • Chemical Shifts
  • Chemical Synthesis
  • Chemistry
  • Electrolysis
  • Liquids
  • Magnetic Resonance
  • Materials
  • Melting Point
  • Nuclear Magnetic Resonance
  • Sodium
  • Sodium Compounds
  • Sodium Hydroxide
  • Spectra
  • Spectrometers
  • Vapor Pressure

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  • Organic Chemistry