TUNNELING PROCESSES ACROSS THE CDSELECTROLYTE INTERFACE,

Abstract

The high-field behavior of the interface between a conducting CdS crystal and a blocking electrolyte contact is studied by the use of pulse techniques. The method employed is very suitable for determining the characteristics of the space-charge region at the crystal surface. In contrast to the case of d.c. measurements, where breakdown of the blocking contact is not apparent up to fields of at least 2x 10,000,000 V/cm, large transient currents through the interface are observed in the range 5 x 1,000,000 to 10,000,000 V/cm. These currents are ascribed to field emission from surface states into the conduction band of the CdS crusta'/ystal. The surface states are shown to be intimately correlated with electrolytically deposited sulphur. (Author)

Document Details

Document Type
Technical Report
Publication Date
Aug 25, 1964
Accession Number
AD0614494

Entities

People

  • A. Many

Organizations

  • RCA Corporation

Tags

DTIC Thesaurus Topics

  • Chemistry
  • Conduction Bands
  • Contrast
  • Electrolytes
  • Electron Emission
  • Emission
  • Energy Bands
  • Field Emission
  • Materials Science
  • Measurement
  • Physics
  • Quantum Tunneling
  • Space Charge
  • Tunneling

Fields of Study

  • Materials science

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Materials Science and Engineering.

Technology Areas

  • Space