INFLUENCE OF FIELD INHOMOGENEITY ON IONIC LINE BROADENING,

Abstract

The usual calculation of the ionic line broadening assumes a constant electric field, acting on an emitting atom. For a many-electron atom the quadratic Stark effect produces a shift proportional to 1/R to the fourth power where R is the distance perturber-atom. The actual Coulomb field of the ions possesses a field gradient, which for levels with a quadrupole moment causes a perturbation with 1/R-cubed. For N independently distributed ions, the probability distribution of the field gradient is calculated. Three approximate cases are discussed: the nearest neighbor approximation, the approximation of spatially fixed eigen-functions, and the nearest neighbour approximation of spatially fixed eigenfunctions. The line profile due to the quasistatic gradient of the field is calculated for these three assumptions. A critical density can be derived by comparing the effect of the field inhomogeneity with the quadratic Stark effect. Below this critical density the effect of the field inhomogeneity dominates. For the example of neutral helium lines the critical density is evaluated and goes up to 10 to the 16th power - 10 to the 17th power particles per cu cm. (Author)

Document Details

Document Type
Technical Report
Publication Date
Sep 21, 1964
Accession Number
AD0615077

Entities

People

  • Karl Gerhard Muller

Organizations

  • Lockheed Martin Missiles and Space

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Atoms
  • Eigenvectors
  • Electric Fields
  • Electrons
  • Mathematics
  • Particles
  • Perturbations
  • Probability
  • Probability Distributions
  • Quadrupole Moment
  • Radiative Transfer
  • Spectroscopy
  • Stark Effect

Fields of Study

  • Physics

Readers

  • Plasma Physics / Magnetohydrodynamics
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.

Technology Areas

  • Microelectronics