QUANTUM MECHANICS OF H02. III. THE NONZERO MATRIX ELEMENTS BETWEEN CONFIGURATIONS BASED ON MAXIMUM PAIRING OF AN ODD NUMBER OF ELECTRONS,

Abstract

A many electron spin eigenfunction is considered constructed from an antisymmetrized linear combination of products of one-electron spin functions and space functions from an orthonormal set for the case of an odd number of electrons with maximum pairing. An explicit representation in terms of one- and two-electron integrals is given for the nonzero Hamiltonian matrix elements involving this function with itself or other similarly constructed functions. By considering permutation of the basis set of space functions, any nonzero matrix element between functions of this form may be obtained from the expressions that are given. (Author)

Document Details

Document Type
Technical Report
Publication Date
May 01, 1965
Accession Number
AD0615659

Entities

People

  • R. H. Knipe

Organizations

  • Naval Air Weapons Station China Lake

Tags

DTIC Thesaurus Topics

  • Eigenvectors
  • Electrons
  • Integrals
  • Mathematics
  • Mechanics
  • Permutations
  • Physical Properties
  • Physics
  • Quantum Mechanics
  • Quantum Properties

Fields of Study

  • Physics

Readers

  • Graph Algorithms and Convex Optimization.
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.

Technology Areas

  • Microelectronics
  • Quantum Computing
  • Space