REACTIONS OF METAL ACETYLACETONATES,
Abstract
Certain metal acetylacetonates undergo reactions characteristic of aromatic systems. Outstanding among these are electrophilic substitutions and the formation of a stable diazonium fluoroborate. Unsymmetrically substituted chelates were prepared by stepwise substitution of trifunctional complexes. Chemical and physical properties of such mixed-ring complexes provide evidence for intramolecular interannular electronic effects transmitted through the metal ion. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Sep 14, 1964
- Accession Number
- AD0616448
Entities
People
- J. P. Collman
Organizations
- University of North Carolina at Chapel Hill