Research on the Deflagration of High-Energy Solid Oxidizers

Abstract

Further experiments have been performed in which the flame temperature above deflagrating hydrazine diperchlorate has been measured with fine thermocouples. A flame temperature of about 1350 deg K is indicated for an ambient pressure of about 20 atmospheres. This is substantially below the theoretical flame temperature of about 1600 deg K. The thermal decomposition of hydrazine diperchlorate has been investigated from 211-291 deg C. The rates of thermal decomposition have been examined and indicate a complex process. Preliminary experiments have been performed on the thermal decomposition of hydrazine diperchlorate-copper chromite mixtures. Ammonium perchlorate has been found in the surface of a strand of hydrazine diperchlorate which had been ignited at an elevated pressure, allowed to deflagrate partially and extinguished by sudden pressure release. Deflagration rate measurements from six to one hundred and thirty atmospheres are reported for pressed hydrazine diperchlorate.

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Document Details

Document Type
Technical Report
Publication Date
May 19, 1965
Accession Number
AD0617272

Entities

People

  • J. B. Levy

Organizations

  • ARCO

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Ammonium Perchlorate
  • Atmospheres
  • Catalysts
  • Chemical Reaction Properties
  • Chemical Reactions
  • Combustion
  • Decomposition
  • Deflagration
  • Energy
  • High Energy
  • Hydrazines
  • Infrared Spectroscopy
  • Measurement
  • Plastic Explosives
  • Spectroscopy
  • Thermal Conductivity
  • Transport Properties

Readers

  • Rocket Propulsion.
  • Thermal Physics or Thermal Science.