THE REFINEMENT OF THE CRYSTAL STRUCTURE OF NORBORNADIENE PALLADIUM CHLORIDE.

Abstract

The crystal structure of norbornadiene palladium chloride has been refined with data obtained by counter methods from crystals maintained at liquid nitrogen temperature. After refinement the conventional discrepancy index R=0.0275. The carbon-carbon single bond distances in the norbornadiene molecule are normal: 1.547, 1.552, 1.554 (=0.006) A; the double bond distances are barely significantly longer than normal: 1.366, 1.366 (=0.010) A. The observed double bond distance is now compatible with the infrared spectrum of the complexed olefin. (Author)

Document Details

Document Type
Technical Report
Publication Date
Aug 12, 1964
Accession Number
AD0617448

Entities

People

  • G. F. Richards
  • J. R. Doyle
  • N. C. Baenziger

Organizations

  • University of Iowa

Tags

DTIC Thesaurus Topics

  • Carbon Carbon Composites
  • Chlorides
  • Crystal Structure
  • Crystals
  • Diffraction
  • Electromagnetic Spectra
  • Infrared Spectra
  • Molecules
  • Nitrogen
  • Palladium
  • Spectra
  • Wave Phenomena

Fields of Study

  • Chemistry

Readers

  • Approximation Theory.
  • Materials Science and Engineering.
  • Polymer Science and Technology