QUANTITATIVE STUDIES BY OPTICAL SPECTROSCOPY OF ENERGY EXCHANGE MECHANISMS IN SIMPLE GASES AND SOLIDS

Abstract

Work has continued in three general directions: condensed phase experiments, emission studies of SiN and N2(+), and plasma analysis. Improvements in apparatus allowed measurement of free carrier mobilities in solid and liquid argon and krypton. As a preliminary to the study of scattering processes, using laser beams, in liquids and van der Waal's solids, equipment and techniques were developed, which allowed observation of Raman and Brillouin scattering in CS2 and benzene liquids. Charge transfer processes in the benzeneiodine complex are being studied at low temperatures using absorption methods. The study has continued of flowing gas systems where the initiating energy source is an electrical discharge. The addition of volatile silicon compounds to active nitrogen has yielded new information on the electronic states of SiN. In a study of N2(+), a detailed perturbation calculation on the mutual interaction between the v = 1 level of the B(2)& state and the v = 11 level of the A(2)pi state were completed. Populations of vibrational and electronic states of N2(+) excited in a helium afterglow were obtained over a large pressure range.

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1965
Accession Number
AD0617797

Entities

People

  • H. D. Pruett
  • H. P. Broida
  • J. L. Dunn
  • J. S. Margolis
  • K. Schofield
  • S. L. Shapiro

Organizations

  • University of California, Santa Barbara

Tags

Communities of Interest

  • Advanced Electronics
  • Ground and Sea Platforms

DTIC Thesaurus Topics

  • Carrier Mobility
  • Charge Transfer
  • Chemical Reactions
  • Electrons
  • Energy
  • Energy Transfer
  • Flow Rate
  • Low Temperature
  • Materials
  • Measurement
  • Mobility
  • Phase
  • Scattering
  • Silicon Compounds
  • Spectra
  • Spectroscopy
  • Transitions

Fields of Study

  • Physics

Readers

  • Materials Science and Engineering.
  • Plasma Physics.

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers
  • Microelectronics