THE INTERACTION OF HYDRAZINE WITH BORON AND ALUMINUM HALIDES,

Abstract

The interaction of boron halides BX3 (where X is Cl or Br) or aluminum halides Al2X6 (where X is Cl, Br, or I) with hydrazine is characterized by the elimination of hydrogen halide and the formation of substances with boron(or aluminum-) nitrogen linkages. The hydrogen halide appears in the products as hydrazine hydrohalide, which can be separated by a hydrazine washing technique, leaving a polymeric material with empirical formula MN4H5 (where M is Al or B). A reaction scheme is proposed and possible structures of this polymeric product are discussed. (Author)

Document Details

Document Type
Technical Report
Publication Date
Feb 26, 1963
Accession Number
AD0617976

Entities

People

  • M. Onyszchuk
  • W. G. Paterson

Organizations

  • McGill University

Tags

DTIC Thesaurus Topics

  • Aluminum
  • Chemical Compounds
  • Chemical Synthesis
  • Chemistry
  • Elements
  • Elimination
  • Hydrazines
  • Hydrogen
  • Materials
  • Materials Science
  • Nitrogen
  • Nonmetals
  • Organic Chemistry
  • Physics

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Surface Engineering/Surface Coating Technology.