SYNTHESIS OF CERTAIN PHYSIOLOGICALLY ACTIVE PHOSPHORO-ORGANIC COMPOUNDS,

Abstract

There were synthesized a series of O-ethyl-S(ethylmercaptoalkyl)-methylthiophosphinates and also Oethyl-O-(beta-ethylmercaptoethyl)-methylphosphinate and O-ethyl-O-(beta-ethylmercaptoethyl)-chloromethylphosphinate which were converted into the corresponding methylsulfomethylates. There were synthesized O-ethylO-(beta-ethylmercaptoethyl)-beta-dimethylaminoalkylphosphinates from which there were obtained the corresponding N-methylsulfomethylates. It was shown that in the action of an equimolecular quantity of dimethylsulfate on O-ethyl-(beta-ethylmercaptoethyl)-dimethylaminoalkylphosphinate there occurs alkylation with the formation of N-methylsulfomethylates, but not S-methylsulfomethylates. (Author)

Document Details

Document Type
Technical Report
Publication Date
Feb 06, 1964
Accession Number
AD0619565

Entities

People

  • E. I. Godyna
  • M. I. Kabachnik
  • N. N. Godovikov

Organizations

  • National Air and Space Intelligence Center

Tags

DTIC Thesaurus Topics

  • Alkylation
  • Organic Compounds

Fields of Study

  • Chemistry

Readers

  • Electrochemical Surface Science
  • Organic Chemistry