TRIFLUOROMETHYL-SUBSTITUTED BORANES. TRIFLUOROMETHYL DI-N-BUTYLBORANE AND TRIFLUOROMETHYLBORON DIFLUORIDE.

Abstract

The preparation and properties of trifluoromethyl di-nbutylborane and trifluoromethylboron difluoride are reported. Loss of difluorocarbene from the trifluoromethyl group bonded to electron-deficient boron was observed in the presence of catalysts but in vacuo at room temperature the substances were stable for months. Infrared spectra and vapor pressure data for n-butylboron difluoride and di-n-butylboron fluoride are reported. (Author)

Document Details

Document Type
Technical Report
Publication Date
Aug 16, 1965
Accession Number
AD0620328

Entities

People

  • James M. Self
  • Lewis H. Schaad
  • Theran D. Parsons

Organizations

  • Oregon State University

Tags

DTIC Thesaurus Topics

  • Catalysts
  • Diffraction
  • Electromagnetic Spectra
  • Electrons
  • Fluorides
  • Infrared Spectra
  • Partial Pressure
  • Spectra
  • Ultraviolet Spectra
  • Vapor Pressure
  • Wave Phenomena

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene