THE MAGNETIC TRANSITION IN WURSTER'S BLUE PERCHLORATE.

Abstract

A study was made of the magnetic transition in Wurster's Blue Perchlorate. From the spectroscopic and magnetic evidence it follows that the transition is due to a disproportionation of the tetra-methyl-p-phenylenediamine ion : TMPD(+) yields TMPD(++) + TMPD. Connected with this is a surprisingly high conductivity in the transition range. (Author)

Document Details

Document Type
Technical Report
Publication Date
Apr 29, 1965
Accession Number
AD0620848

Entities

People

  • Gerard T. Pott
  • Jan Kommandeur

Tags

DTIC Thesaurus Topics

  • Amines
  • Chemical Compounds
  • Chemical Reactions
  • Chlorine Compounds
  • Conductivity
  • Disproportionation
  • Halogen Compounds
  • Perchlorates
  • Phenylenediamines
  • Transitions

Fields of Study

  • Physics

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Materials Science and Engineering.