SEPARATION OF TAGGED COMPOUNDS BY THE METHOD OF GASEOUS CHROMATOGRAPHY,

Abstract

Trimethylethoxysilane and dimethylethoxysilane that had been tagged with deuterium were separated by preparative gaseous chromatography. The basis part of the chromatograph was a column of 2-meter steel tubes with 30-mm diameter, connected by U-shaped passages, so that the column was 7 meters long in all. The samples were vaporized and fed by a nitrogen gas carrier stream into the column where they were subdivided into their components. The divided fractions were directed, with the aid of a sampling device of 7 electromagnetic valves, into proper traps where they were frozen out by liquid nitrogen. At a working temperature of the column of about 100C, mixtures of compounds with boiling points up to 160-170 C could be separated.

Document Details

Document Type
Technical Report
Publication Date
Aug 26, 1965
Accession Number
AD0621010

Entities

People

  • K. I. Sakodynskii
  • S. A. Volkov

Organizations

  • National Air and Space Intelligence Center

Tags

DTIC Thesaurus Topics

  • Boiling
  • Boiling Point
  • Chromatographs
  • Chromatography
  • Deuterium
  • Diameters
  • Elements
  • Isothermal Processes
  • Nitrogen
  • Nonmetals
  • Phase Transformations
  • Physical Properties
  • Sampling
  • Thermodynamic Processes

Readers

  • Aerosol Science/Aerosol Physics
  • Combustion and Flow Dynamics.
  • Organic Chemistry