SULFENIC ACIDS AND THEIR DERIVATIVES. XLI. SULFENYL NITRATES AND SULFINYL RADICALS,
Abstract
Sulfenyl nitrates, RSONO2, represent a novel class of sulfenyl compounds. The preparation of the first examples is described and some of their properties are recorded. The near-quantitative conversion of sulfenyl nitrates to thiolsulfonate esters (2 RSONO2 yields RSO2SR + 2NO2) is demonstrated and interpreted as a dimerization reaction of sulfinyl radicals. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 01, 1965
- Accession Number
- AD0621222
Entities
People
- Norman Kharasch
- Richard M. Topping
Organizations
- University of Southern California