RESEARCH ON RARE EARTH FLUORIDE MATERIALS.

Abstract

The work reported is directed toward the selection of those high quality rare earth fluoride materials which indicate the most promising host and dopant combinations, with optimum dopant concentrations, for laser applications. Rare earth materials purified by ion exchange indicated a significant improvement in crystal quality. Single crystals of LaF(3) doped with Tb(3+), Tm(3+), Yb(3+), and Ce(3+), in addition to two new hosts - DyF3 and CeF3, were grown for spectroscopic evaluation. DyF3 will be further investigated as a host sensitizer for Pr(3+). Samples of CeF3:Nd(3+) were prepared for laser testing. Crystals of Er(3+) and Er(3+)-Ce(3+)-doped LaF3 were prepared for further study of the quenching of Er(3+) by Ce(3+); this quenching may be accounted for by ion pair interaction. Theoretical considerations of cross relaxation in double-doped systems are discussed. (Author)

Document Details

Document Type
Technical Report
Publication Date
Aug 31, 1965
Accession Number
AD0622338

Entities

People

  • A. G. Hastings
  • C. K. Asawa
  • D. P. Devor
  • Michael Robinson
  • O. M. Stafsudd

Organizations

  • HRL Laboratories

Tags

DTIC Thesaurus Topics

  • Crystals
  • Fluorides
  • Ion Exchange
  • Laser Applications
  • Lasers
  • Materials
  • Quenching
  • Single Crystals
  • Test And Evaluation

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.

Technology Areas

  • Directed Energy
  • Directed Energy - Pulsed-Laser Deposition