THE THERMAL DECOMPOSITION OF METAL ETHYLENEDIAMINE OXALATE COMPLEXES,

Abstract

The thermal dehydration and deamination of some ethylenediamine complexes of Zn, Cd, Cu, Ni, and Co oxalate were studied by thermogravimetry, differential thermal analysis, differential scanning calorimetry, high temperature reflectance spectroscopy, and gas evolution. The tris(ethylenediamine) complexes deaminated to mono(ethylenediamine) compounds which then decomposed directly to the metal oxide. The kinetics and heats of dehydration and deamination of several of the complexes were determined. (Author)

Document Details

Document Type
Technical Report
Publication Date
Aug 07, 1964
Accession Number
AD0622847

Entities

People

  • John M. Haschke
  • Wesley W. Wendlandt

Organizations

  • Texas Tech University

Tags

DTIC Thesaurus Topics

  • Calorimetry
  • Decomposition
  • Dehydration
  • Differential Thermal Analysis
  • Energy
  • Ethylenediamine
  • Gas Evolution
  • Heat Energy
  • High Temperature
  • Kinetics
  • Metal Oxides
  • Oxides
  • Personal Information Managers
  • Physics
  • Reflectance
  • Thermal Analysis

Fields of Study

  • Chemistry

Readers

  • Analytical Chemistry
  • Combustion science or combustion engineering.
  • Electrochemical Surface Science