EFFECT OF A FERROCENYL SUBSTITUTE ON THE FUNCTIONAL GROUPS IN THE BENZENE RING,
Abstract
The dissociation constants K-a and K-b were obtained for several ferrocenyl substituted benzoids and were compared with these constants for amino and hydroxy substituted benzoids. The K-b of p-Ferrocenylaniline is 3 times greater than that of aniline, and 17 times greater than that of p-aminodiphenyl (xenylamine); the K-b of m-ferrocenylanaline is 2/3 as great as the p- isomer. Similar results were obtained by the comparison of ferrocenylamine and ferrocenylphenol with phenol and p-hydroxydiphenyl (p-phenylphenol), indicating that the ferrocenyl group introduced into the benzene ring behaves as a distinctly expressed substitute of the first order.
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 01, 1965
- Accession Number
- AD0623781
Entities
People
- A. N. Nesmeyanov
- E. G. Perevalova
- R. V. Golovnya
Organizations
- National Air and Space Intelligence Center