SIB POLYMER DEVELOPMENT.

Abstract

Further studies with the recently discovered 'offratio' SiB-2 rubber confirmed that it is possible to make a SiB elastomer with 1,000 to 1,200 pounds tensile strength, although this species leaves something to be desired in heat resistance. A particularly interesting SiB representative was included in our investigation since the last report. Chemically it is a phenyl substituted SiB-4 polymer which can be obtained not only in the usual rubbery form but also as a viscous stock. Vulcanizates from this latter material exhibit outstanding heat-aging resistance surpassing the performance of any rubber we have seen so far. In addition, it was found to be still flexible as -80F, thus indicating a wide range of elasticity. The investigation of antioxidants such as ferric oxide, tungsten oxide and ferrocene was intensified. The two oxides, especially, impart noteworthy resistance to deterioration of the polymers at elevated temperatures.

Document Details

Document Type
Technical Report
Publication Date
Nov 19, 1965
Accession Number
AD0624544

Entities

People

  • H. A. Schroeder
  • O. G. Schaffling

Tags

DTIC Thesaurus Topics

  • Amorphous Materials
  • Antioxidants
  • Biomedical And Dental Materials
  • Elastic Properties
  • Elastomers
  • Ferrocenes
  • Films
  • Materials
  • Oxides
  • Polymeric Films
  • Polymers
  • Resistance
  • Tensile Strength
  • Tungsten
  • Tungsten Oxides
  • Vulcanizates

Fields of Study

  • Materials science

Readers

  • Organic Chemistry
  • Polymer Science and Engineering.