ZEEMAN SPLITTING OF NARROW LINES IN CRYSTALLINE MNF2, FEF2, AND COF2. EVIDENCE FOR SPIN-WAVE EXCITATIONS.

Abstract

The Zeeman splitting of narrow lines in the optical spectrum of crystals of MnF2, FeF2, and CoF2 was measured at 4.2 K and in applied magnetic fields to 170 kG. All of the transitions observed are intercombinations for which delta S = -1. These crystals all have the rutile structure. The behavior of narrow lines in the 5450 A region of the MnF2 spectrum is shown as the external magnetic field is applied parallel to the c axis (z direction) of the crystals. The lines arise from transitions from the ground (6)A sub 1g state to the lowest (4)T sub 1g excited state and are at slightly lower energy than the vibronic band for this transition. Similar results for the 3800 A region of FeF2 are shown. In each case two magnetic dipole transitions, separated by 17.2/cm for MnF2 and 35.9/cm for FeF2 appear, followed at higher energies by electric dipole transitions. The latter do not split in the external magnetic field, in the case of MnF2, and split less than half as much as the magnetic dipole lines in the case of FeF2.

Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1965
Accession Number
AD0624803

Entities

People

  • Donald S. Mcclure
  • J. W. Stout
  • Philip G. Russell

Organizations

  • University of Chicago

Tags

DTIC Thesaurus Topics

  • Diffraction
  • Dipoles
  • Electromagnetic Spectra
  • Excitation
  • Magnetic Dipoles
  • Magnetic Fields
  • Spectra
  • Spin Waves
  • Splitting
  • Transitions
  • Wave Phenomena

Fields of Study

  • Physics

Readers

  • Materials Science and Engineering.
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.