RESEARCH ON SYNTHESIS OF UNSATURATED FLUOROCARBON COMPOUNDS

Abstract

The purpose of the project is to conduct the necessary research for the preparation of unsaturated organic compounds containing fluorine and to prepare various fluorolefins which may give elastomers which are oil and fuel resistant and which retain their elasticity at low temperatures. The preparation of perfluoroallyl chloride was improved and this compound was treated with various alkoxide ions to product saturated and unsaturated ethers. Lewis acid catalysed additions of polyhaloalkanes to haloolefins were continued. In an attempt to prepare fluoronitroso compounds carrying other functional groups, nitrosyl chloride was allowed to react with unsaturated fluoroesters and ethers. The investigation of the radical addition of haloalkyl chlorides and bromides with various olefins was continued. Attempts were made to react radicals from CF2BrCFClBr and CF2ClCFCII with aromatic nuclei.

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Document Details

Document Type
Technical Report
Publication Date
Sep 30, 1965
Accession Number
AD0624867

Entities

People

  • Alan Wright
  • Doug Perry
  • Jai Tandon
  • Paul Tarrant
  • Susumu Misaki

Organizations

  • University of Florida

Tags

Communities of Interest

  • Counter WMD

DTIC Thesaurus Topics

  • Abstracts
  • Alcohols
  • Alkenes
  • Benzoic Acids
  • Chemical Products
  • Chemical Synthesis
  • Chemistry
  • Copper
  • Dermatologic Agents
  • Exothermic Reactions
  • Halides
  • Infrared Spectra
  • Materials
  • Nitroso Compounds
  • Organic Chemistry
  • Spectra

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Polymer Science and Engineering.