AN INFRARED STUDY OF POLYFLUORINATED AROMATICS IN THE LOW-FREQUENCY REGION.

Abstract

By use of the inequality rule and comparison with chlorobenzenes, the out-of-plane CF deformations of a series of unsubstituted fluorobenzenes were assigned. Tentative assignments were also made for the in-plane CF deformations. The CF deformations of a series of substituted pentafluorobenzenes were assigned and were shown to correlate with the frequencies of the unsubstituted pentafluorobenzenes. While it is not possible to use only one band for identification of ring substitution (as in the case of using CH deformations), the entire pattern of CF deformations can be used for analytical purposes. (Author)

Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1965
Accession Number
AD0625125

Entities

People

  • R. J. Jakobsen

Organizations

  • Battelle Memorial Institute

Tags

Communities of Interest

  • Air Platforms

DTIC Thesaurus Topics

  • Aromatic Compounds
  • Aromatic Hydrocarbons
  • Benzene Compounds
  • Chemical Compounds
  • Chlorobenzene
  • Frequency
  • Halogenated Hydrocarbons
  • Hydrocarbons
  • Identification
  • Inequalities

Readers

  • Organic Chemistry
  • Regression Analysis.
  • Structural Dynamics.